You say it's not rational but what if it is due to deep seeded feelings around Nick and Rosalee. I have been saying that on the surface, Juliette seemed to be accepting of her lot with Nick once she found out about him being a Grimm, but perhaps she was much more negatively affected than she openly let on with all the crap that has happened to her since the cat scratch, perhaps she wanted to be okay because she loved Nick for so long and Rosalee and had become good friends by association. Once she got her powers, they heightened all that negativity festering on the inside. She went from being content to resentful, from feeling safe to fearing for her life based on past experiences (Nick's hatred for Adalind) that he wouldn't see past the "monster" she had become. It may seem irrational because as an outsider we have see the whole picture but for Juliette, in that moment she was overwhelmed by the changes and Nick's inability to look past the changes. it's not irrational to her, she drew a conclusion, albeit a wrong one and everything crumbled from that point onward.
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